- Navigating the World of Chinese Interior Wall Coating Lacking Lead
Anatase titanium dioxide is a popular ingredient in coatings due to its excellent UV resistance and chemical stability. Many manufacturers and businesses rely on wholesale suppliers to provide high-quality anatase titanium dioxide for their coating applications.
Fluorine Chemical, Lithopone 30% CAS No. 1345-05-7, white powder, relative density: 4.136 ~ 4.39 g / mL, insoluble in water. It is a mixture of zinc sulfide and barium sulfate. Inorganic white pigment, widely used in plastics such as polyolefin, vinyl resin, ABS resin, polystyrene, polycarbonate, nylon and polyoxymethylene, and white pigments of paints and inks. It is less effective in polyurethane and amino resins and less suitable in fluoroplastics. It is also used for coloring of rubber products, paper, varnish, tarpaulin, leather, watercolor paint, paper, enamel, and the like. Used as a binder in the production of electric beads.
When used in food specifically, titanium dioxide is known as an additive called E171 and can be found in products like candy, chocolate, coffee creamer, cake decorations, chewing gum and even vitamin supplements. E171 is often used as coloring additive in foods, to lend the processed item a natural whiteness and opacity — such as in Skittles candy, where it's used as a white base to help give the candies their signature bright, colorful hue.
The successful completion of 2022. Looking at the development of Titanium Dioxide market in this year, from the perspective of price, according to the monitoring of bulk commodity data, the price of titanium dioxide will fall in 2022. The average price of domestic titanium dioxide at the beginning of the year was 20733.33 yuan/ton, and the average price at the end of the year was 15933.33 yuan/ton. The price fell by 23.15% during the year.
2. Market analysis
Product quotation
From the perspective of market development in 2022, prices in the first half of the year are basically in a stable stage, with little fluctuation, and prices in the second half of the year are in a rapid decline stage. In November, Longqi sent a letter to raise the price to stabilize the price. At this time, the price of titanium dioxide began to stabilize and stop falling.
In the first quarter, export orders performed well, and the market confidence of titanium dioxide enterprises was good. Before the year, domestic downstream manufacturers mainly hoarded goods moderately before the year. The market rose twice, with a cumulative increase of 1.77% from January to March. The ex factory quotation of domestic rutile titanium dioxide including tax is mostly 20000-22000 yuan/ton; The ex factory quotation of anatase titanium dioxide including tax is between 18000-19500 yuan/ton. After the year, the domestic raw material sulfuric ACID price continued to rise, the enterprise cost was under pressure, and the support was strong. The titanium dioxide market confidence was fair, and the price continued to rise.
In the second quarter, the logistics management and control and the domestic market turnover were light. Affected by logistics control and other factors, transportation is relatively difficult, market supply is shrinking, traders are unstable, and the market price declines with the focus on digesting their own inventory. The cumulative decline from April to June was 3.08%. The ex factory quotation of domestic rutile titanium dioxide including tax is between 19100-22000 yuan/ton; The ex factory quotation of anatase titanium dioxide including tax is between 17800-19000 yuan/ton. The spot market of titanium ore continued to decline, the price of sulfuric acid also continued to decline, and the cost support was weak. At the same time, the performance of the downstream terminal real estate market is poor. Under the superposition of multiple negative factors, the titanium dioxide market fell.
In the third quarter, Longqi guided the price reduction and the titanium dioxide market fell sharply. 7-9 The cumulative decline was 19.85%. The ex factory quotation of domestic rutile titanium dioxide including tax is mostly between 15500-17000 yuan/ton; The quotation of anatase titanium dioxide is between 14500-15500 yuan/ton. Due to the limited power supply and other factors, the titanium dioxide enterprises in southwest China have reduced their production. The market price of raw sulfuric acid fell rapidly, and the cost support was weak. In addition, the domestic titanium dioxide market demand continues to be sluggish, and the manufacturer's inventory pressure is still large.
In the fourth quarter, Dragon Enterprise sent a letter in November to promote stability. The cumulative decline was 2.55% from October 12. The titanium dioxide market is about to enter the off-season, and the demand market for coatings is tepid, especially in the northern market. In November, the group announced that the price would rise, and the prices offered by various manufacturers were flexible, so it was more meaningful to stop the decline. Most domestic rutile titanium dioxide prices are between 15000-17500 yuan/ton; The quotation of anatase titanium dioxide is about 14000-14500 yuan/ton. The price of titanium concentrate in Panxi increased. More than 20 domestic titanium dioxide enterprises sent letters to announce the increase, and the international giants Chemurs and Tronox announced the reduction of titanium dioxide production in the fourth quarter, which also benefited the domestic titanium dioxide market and stabilized the market on the whole.
1. What is titanium dioxide?
At present, the equipment and manufacturing process of domestic manufacturers of polyvinyl butyral are constantly getting closer to those abroad. For example, the wonderful use of polyvinyl butyral (PVB) has occurred in the printing industry and ceramic industry. Therefore, the domestic application of polyvinyl butyral (PVB) has an obvious upward trend in recent years.
For example, in the glass industry, it is because polyvinyl butyral (PVB) has good low-temperature impact strength, windability, light transmittance, light resistance, weather resistance, sound insulation, UV insulation and other properties, so that once the laminated glass is sealed together, the glass sandwich (i.e. laminated material) will appear as a whole and look like ordinary glass. For example, in the porcelain industry, polyvinyl butyral is made into a film and used for printing paper film of ceramic (or enamel) products. First, it reduces the original glue small paper Decal process, reduces the production cycle and production cost, and second, it makes its ceramic (or enamel) patterns bright in color and smooth in texture.
With the rapid development of science and technology in recent years, more and more industries have found the characteristics of polyvinyl butyral (PVB): high strength, high toughness, fatigue resistance, corrosion resistance and so on. Compared with traditional materials, polyvinyl butyral (PVB) is more and more widely used because of its larger development space and wider application fields!
Application field of polyvinyl butyral -- safety glass
The membrane made of polyvinyl butyral (PVB) is a special product used to manufacture safety glass and bulletproof glass. Safety glass is a special glass made of a layer of PVB diaphragm sandwiched between two layers of ordinary glass. It has good low-temperature impact strength, windability, light transmittance, light resistance, weather resistance, sound insulation, ultraviolet insulation and other properties. When subjected to strong external impact, PVB diaphragm can absorb impact energy, so that the glass will not break or prevent debris from hurting people. Moreover, the safety glass added with PVB diaphragm has the characteristics of high transparency, water resistance and aging resistance, and can be used in the environment of - 60 ℃. In addition, it can also be used as transparent material to replace plexiglass.
Application field of polyvinyl butyral -- ceramic film flower paper
2: Clarification mechanism of coagulant
Chemical coagulation is a process in which chemical agents (coagulants) are added to water treatment to make colloidal dispersion system destabilize and agglomerate. In the coagulation process, small suspended particles and colloidal impurities are aggregated into larger solid particles to separate particulate impurities from water, which is called coagulation clarification.
After adding coagulant into water, colloidal particles and other small particles can be polymerized into larger flocs through the comprehensive action of mixing, coagulation and flocculation. The whole process of coagulation and flocculation is called coagulation.
(1) Destabilization and condensation of colloids
Adding electrolyte to water can compress the electric double layer and destabilize the colloid. The main mechanism is that the electric double layer of colloidal particles in water is compressed or neutralized by adding aluminum salt or iron salt coagulant. The coagulant and raw water are mixed rapidly and evenly, and a series of chemical reactions are produced to destabilize. This process takes a short time, generally about 1 min. Some cationic polymers can also play a role in the destabilization and condensation of colloids in water. These polymers have a long chain structure and positive charge in water. Their destabilization and condensation of colloids in water is due to the interaction of van der Waals force adsorption and electrostatic attraction.
(2) Flocculation and formation of floc (alum)
The particle size of the initial flocculate formed by colloid destabilization and coagulation in water is generally more than 1 m. at this time, Brownian motion can no longer push them to collide and form larger particles. In order to make the initial flocs collide with each other to form large flocs, it is necessary to input additional energy into the water to produce a velocity gradient. Sometimes it is necessary to add organic polymer flocculant into water, and the adsorption bridging effect of long chain molecules of flocculant is used to improve the probability of collision and adhesion. Flocculation efficiency usually increases with the increase of flocculate concentration and flocculation time.
Compared with polyaluminum chloride, polyaluminum chloride has the advantages of high density, fast settling speed and wide pH adaptability; the coagulation effect is less affected by temperature than that of polyaluminum sulfate; however, when adding ferric salt, it should be noted that when the equipment is not in normal operation, the iron ions will make the effluent color, and may pollute the subsequent desalination equipment.
Journalism
The most common foods containing titanium dioxide are chewing gum, candies, pastries, chocolates, coffee creamers, and cake decorations (1Trusted Source, 3Trusted Source).
The CaCO3 and TiO2 factory plays a crucial role in producing these materials on a large scale to meet the growing demand from various industries. The factory utilizes advanced technology and processes to extract and refine CaCO3 and TiO2 from natural resources such as limestone and mineral sands. The production process involves crushing, grinding, and chemical treatment to obtain the desired properties of CaCO3 and TiO2.
CAS registration number: 1345-05-7
After conducting a review of all the relevant available scientific evidence, EFSA concluded that a concern for genotoxicity of TiO2 particles cannot be ruled out. Based on this concern, EFSA’s experts no longer consider titanium dioxide safe when used as a food additive. This means that an Acceptable Daily Intake (ADI ) cannot be established for E171.
Lithopone’s historical significance is further accentuated by the advancements and modifications that followed its inception. The 1874 patent by J.B. Orr, for instance, ushered in a new white pigment—Orr’s Zinc White. This innovation was attained by co-precipitating zinc sulfate and barium sulfide, followed by a calcination process. Further refinements marked the subsequent decades, the most notable being the enhancement of lightfastness achieved in the 1920s by introducing small amounts of cobalt salts before calcination.
Price Dynamics. The Titanium Dioxide price in United States decreased during December 2018 to 2,770 USD per metric ton, which represents a decline of 7% compared to the previous month’s value. On a year-over-year basis, Titanium Dioxide prices in United States remained constant . Meanwhile, in Germany, the average price of Titanium Dioxide amounted to 3,720 USD per metric ton, from 3,460 USD per metric ton one year earlier. On a month-over-month basis, the Titanium Dioxide price in Germany is 11% higher than the price one month before.
With the increasing demand for titanium dioxide in various industries, the search for reliable suppliers has become crucial. Among the numerous suppliers in the market, r 996 titanium dioxide suppliers have emerged as one of the leading suppliers in the industry.
The produced barium sulfide enters the leacher, and the temperature is controlled above 65°C to obtain a barium sulfide content of 70%, and then enters the clarification barrel, add zinc sulfate for reaction after clarification, control the zinc sulfate content to be greater than 28%, pH=8~9, and obtain a mixture of barium sulfate and zinc sulfide with a density of 1.296~1.357 g/cm3.
Although barium sulfate is almost completely inert, zinc sulfide degrades upon exposure to UV light, leading to darkening of the pigment. The severity of this UV reaction is dependent on a combination of two factors; how much zinc sulfide makes up the pigments formulation, and its total accumulated UV exposure. Depending on these factors the pigment itself can vary in shade over time, ranging from pure white all the way to grey or even black. To suppress this effect, a dopant may be used, such as a small amount of cobalt salts, which would be added to the formulation. This process creates cobalt-doped zinc sulfide. The cobalt salts help to stabilize zinc sulfide so it will not have as severe a reaction to UV exposure.
Technical Specifications:(Standard:Q/SNBJ1-2012)